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Laser Properties of Nd:YVO4

1. One of the most attractive character of Nd:YVO4 is, compared with Nd:YAG, it has 5 times larger absorption coefficient in a broader absorption bandwidth around the 808 nm peak pump wavelength, which just matches the standard of high power laser diodes currently available. This means a smaller crystal that could be used for the laser, leading to a more compact laser system. For a given output power, this also means a lower power level at which the laser diode operates, thus extending the lifetime of the expensive laser diode. The broader absorption bandwidth of Nd:YVO4 which may reaches 2.4 to 6.3 times that of Nd:YAG, is also valuable. Besides more efficient pumping, it also means a broader range of selection of diode specifications. This will be helpful to laser system makers for wider tolerance and lower cost choice.

2. Nd:YVO4 crystal has larger stimulated emission cross-sections, both at 1064nm and 1342nm. When a-axis cut Nd:YVO4 crystal lasing at 1064m, it is about 4 times higher than that of Nd:YAG, while at 1340nm the stimulated cross-section is 18 times larger, which leads to a CW operation completely outperforming Nd:YAG at 1320nm. These make Nd:YVO4 laser be easy to maintain a strong single line emission at the two wavelengths.

3. Another important character of Nd:YVO4 lasers is, because it is an uniaxial rather than a high symmetry of cubic as Nd:YAG, what it emits is only a linearly polarized, thus avoiding undesired birefringent effects on the frequency conversion. Although the lifetime of Nd:YVO4 is about 2.7 times shorter than that of Nd:YAG, its slope efficiency can be still quite high for a proper design of laser cavity, because of its high pump quantum efficiency.

The major laser properties of Nd:YVO4 vs Nd:YAG are listed in Table below, including stimulated emission cross-sections (σ), Absorption Coefficient (α) Fluorescent lifetime (τ),Absorption Length (La),threshold Power (Pth) and Pump Quantum Efficiency (
ηs).

Laser Properties of Nd:YVO4 vs Nd:YAG

LASER CRYSTAL

DOPING(atm%)

σ
(x10-19cm2)

α
(cm-1)

τ
(μs)

Lα
(mm)

Pth
(mW)

ηs
(%)

Nd:YVO4(a-cut)

1.0
2.0

25
25

31.2
72.4

90
50

0.32
0.14

30
78

52
48.6

Nd:YVO4(c-cut)

1.1

7

9.2

90

 

231

45.5

Nd:YAG

0.85

6

7.1

230

1.41

115

38.6

Typical Results:
•Diode pumped Nd:YVO4 laser output comparing with diode pumped Nd:YAG laser.

Crystals

Size(mm3)

Pump Power

Output (at 1064nm)

Nd:YVO4

3x3x1

850mW

350mW

Nd:YVO4

3x3x5

15W

6W

Nd:YAG

3x3x2

850mW

34mW

 Diode pumped Nd:YVO4+KTP green laser.

  • 8W green laser was generated from a 15W LD pumped 0.5% Nd:YVO4 with intracavity KTP.
  • 200mW green outputs are generated from 1W LD pumped 2% Nd:YVO4 lasers by using LaserMa’s 2x2x5mm KTP and 3x3x1mm Nd:YVO4

LASERMA provides the following coatings

  • Both ends AR/AR-1064/808nm, R<0.2%@1064nm,R<2%@808nm
  • S1:HR@1064&532 nm,HT808 nm, R>99.8%@1064&532nm,T>90%@808nm S2:AR@1064&532 nm, R<0.2%@1064nm,R<0.5%@532nm
  • S1:HR@1064,HT808, R>99.8%@1064nm,T>95%@808nm S2:AR@1064, R<0.1%@1064nm.
  • S1,S2 AR-coated, S3:gold/chrome plated.
  • Both ends AR/AR-1064 nm; S3:AR-808 nm
  • Other coatings are available upon request.

LASERMA Warranty on Nd:YVO4 Specifications:

 Dimension tolerance:(W±0.1mm)x(H±0.1mm)x(L+0.5/-0.1mm)  (L≥2.5mm)
(W±0.1mm)x(H±0.1mm)x(L+0.2/-0.1mm)  (L<2.5mm
 Transmitting wavefront distortion:less than λ/4 @ 633nm
 Clear aperture:>90% central area
 
Chamfer: ≤0.2mm@45
 Chip: ≤0.1mm
 Flatness: λ/8 @ 633 nm (L≥2.5mm), λ/4 @ 633nm  (L<2.5mm)
 Scratch/Dig code: 10/5 to MIL-PRF-13830B
 Parallelism:better than 20 arc seconds
 Perpendicularity: 5 arc minutes
 Angle tolerance:0.5°
 Damage threshold[GW/cm2 ]: >1 for 1064nm, TEM00, 10ns, 10Hz (AR-coated)
 Quality Warranty Period:one year under proper use.

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